Dehydrogenative 6π heterocyclization under visible light irradiation and mechanistic insights-Reference-Cited by-同舟云学术

Dehydrogenative 6π heterocyclization under visible light irradiation and mechanistic insights

Published:2021 Issue:14 Volume:8 Page:3788-3795
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Zhao¹²³⁴⁵,Chen Haohua⁶⁷⁸⁹¹⁰,Keller Niklas¹¹¹²¹³¹⁴^ORCID,Xiong Qin⁶⁷⁸⁹¹⁰,Liu Lei¹⁵¹⁶¹⁷¹⁰,Lan Yu⁶⁷⁸⁹¹⁰^ORCID,Bein Thomas¹¹¹²¹³¹⁴,Li Jie¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province

2. College of Chemistry

3. Chemical Engineering and Materials Science

4. Soochow University

5. 215123 Suzhou

6. School of Chemistry and Chemical Engineering

7. and Chongqing Key Laboratory of Theoretical and Computational Chemistry

8. Chongqing University

9. Chongqing 400030

10. China

11. Department of Chemistry

12. Ludwig-Maximilians-Universität München (LMU)

13. 81377 Munich

14. Germany

15. School of Pharmaceutical Science

16. Jiangnan University. Lihu Avenue 1800

17. 214122 Wuxi

Abstract

A visible-light-driven oxidative 6π heterocyclization for the synthesis of structurally diverse π-conjugated polycyclic 1-aminoisoquinolines has been developed. DFT calculations demonstrated that deprotonation is the rate-determining step.

Funder

National Natural Science Foundation of China

Soochow University

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00356A

Reference65 articles.

1. Functionalized Acenes and Heteroacenes for Organic Electronics