Monomolecular VB2-doped MOFs for photocatalytic oxidation with enhanced stability, recyclability and selectivity

Author:

Zhang Ruoqian1234,Song Xinhua1234,Liu Yuanyuan1234,Wang Peng1234ORCID,Wang Zeyan1234ORCID,Zheng Zhaoke1234,Dai Ying524ORCID,Huang Baibiao1234ORCID

Affiliation:

1. State Key Laboratory of Crystal Materials

2. Shandong University

3. Jinan 250100

4. China

5. School of Physics

Abstract

Monomolecular VB2 was immobilized onto UiO-66 taking advantage of the ligand defects in the latter, and 1O2 became the only reactive oxygen species, resulting in high selectivity towards benzyl alcohol oxidation.

Funder

National Natural Science Foundation of China

Taishan Scholar Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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