Influence of the organic cation on the formation of hexahalotechnetates: X-ray, thermal and comparative analyses of non-covalent interactions-Reference-Cited by-同舟云学术

Influence of the organic cation on the formation of hexahalotechnetates: X-ray, thermal and comparative analyses of non-covalent interactions

Published:2023 Issue:46 Volume:52 Page:17538-17547
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Novikov Anton P.¹^ORCID,Zagidullin Karim A.¹^ORCID,Volkov Mikhail A.¹^ORCID,German Konstantin E.¹^ORCID,Nevolin Iurii M.¹,Grigoriev Mikhail S.¹

Affiliation:

1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IPCE RAS), 31 Bldg 4, Leninsky prosp., Moscow, 119071, Russian Federation

Abstract

Eight new compounds of hexachlorotechnetate(iv) were synthesized and characterized. A comparative analysis of non-covalent interactions was conducted, and the dependence of the thermal stability of the synthesized compounds was investigated.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT03235C

Reference72 articles.

1. High-Valent Technetium Complexes with the [99TcO3]+ Core from in Situ Prepared Mixed Anhydrides of [99TcO4]- and Their Reactivities

2. Studies of technetium complexes. Part 6. The preparation, characterisation, and electron spin resonance spectra of salts of tetrachloro- and tetrabromo-nitridotechnetate(VI): crystal structure of tetraphenylarsonium tetrachloronitridotechnetate(VI)

3. New O- and N-N-Bridging Complexes of Tc(V), the Role of the Nitrogen Atom Position in Aromatic Rings: Reaction Mechanism, Spectroscopy, DTA, XRD and Hirshfeld Surface Analysis

4. Reactions of pertechnetate anion with triphenylphosphine. Molecular structure (at –100 °C) of (1,1-dimethyl-3-oxobutyl)triphenylphosphonium pentachloro(triphenylphosphine)technetate(IV)

5. Reactions of [MCl6]2? (M=Tc or Re) with salicylaldehyde. The molecular structure of tetraphenylphosphonium tetrachloro(salicylaldehydato) technetate (IV)