Construction of C(sp2)–S and C(sp2)–Se bonds via a silver(i)-mediated coupling reaction of heterocyclic ketene aminals with diaryl dichalcogenides-Reference-Cited by-同舟云学术

Construction of C(sp2)–S and C(sp2)–Se bonds via a silver(i)-mediated coupling reaction of heterocyclic ketene aminals with diaryl dichalcogenides

Published:2014 Issue:50 Volume:4 Page:26389-26397
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Jiang Xiu-Yang¹²³⁴⁵,Liu Zhi-Cheng¹²³⁴⁵,Fang Li¹²³⁴⁵,Yan Sheng-Jiao¹²³⁴⁵,Lin Jun¹²³⁴⁵

Affiliation:

1. Key Laboratory of Medicinal Chemistry for Natural Resource (Yunnan University)

2. Ministry of Education

3. School of Chemical Science and Technology

4. Yunnan University

5. Kunming, P. R. China

Abstract

A novel Ag(i)-mediated direct coupling reaction using HKAs and diaryl dichalcogenides for the construction of C(sp²)–chalcogenide bonds is reported. The transformation leads to a variety of α-arylthio and α-phenylselanyl HKAs with high regioselectivity and excellent yields.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA02519A

Reference74 articles.

1. Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

2. Carbon–heteroatom bond formation catalysed by organometallic complexes

3. Metal-catalyzed nucleophilic carbon–heteroatom (C–X) bond formation: the role of M–X intermediates

4. Transition-metal-catalyzed reactions of carbon-heteroatom bond formation by substitution and addition processes

5. Transition Metal-Catalyzed Cross-Coupling and the Heck Coupling Processes: Powerful Reactions for Carbon-Carbon and Carbon-Heteroatom Bond Formation

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Direct Access to Thio- and Seleno-acetamides Bearing (Benzo)thiazoles by a Base-Promoted One-Pot Two-Step Three-Component Reaction of 2-Amino(benzo)thiazoles with Aryl Acetyl Chlorides and Dichalcogenides;The Journal of Organic Chemistry;2024-03-02

2. Ag‐Catalyzed/Mediated CX Bond Formation (X = P, S, Se) Through CH Bond Functionalization;Handbook of CH‐Functionalization;2022-10

3. 1,3-Diazepines;Comprehensive Heterocyclic Chemistry IV;2022

4. Meyer–Schuster-Type Rearrangement of Propargylic Alcohols into α-Selenoenals and -enones with Diselenides;The Journal of Organic Chemistry;2021-03-12

5. Copper-catalyzed direct oxidative C(sp 2 )-H α -sulfenylation of enaminones with disulfides or thiophenols: Synthesis of polyfunctionalized aminothioalkenes;Tetrahedron Letters;2018-04