Mechanistic insights into dioxygen activation by a manganese corrole complex: a broken-symmetry DFT study-Reference-Cited by-同舟云学术

Mechanistic insights into dioxygen activation by a manganese corrole complex: a broken-symmetry DFT study

Published:2021 Issue:40 Volume:11 Page:24852-24861
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yu Jiangfeng¹²³⁴,Lai Wenzhen¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Renmin University of China

3. Beijing

4. China

Abstract

DFT calculations revealed a novel mechanism for the formation of Mn(v)–oxo in the dioxygen activation by a Mn(iii) corrole complex involving a Mn(iii)–alkylperoxo intermediate.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA02722K

Reference82 articles.

1. Dioxygen Activation by Metalloenzymes and Models

2. Oxygen activation by mononuclear nonheme iron dioxygenases involved in the degradation of aromatics

3. Mechanistic dichotomies in redox reactions of mononuclear metal–oxygen intermediates

4. Hydrogen Atom Transfer Reactions of Mononuclear Nonheme Metal–Oxygen Intermediates

5. Factors Affecting Hydrogen Atom Transfer Reactivity of Metal–Oxo Porphyrinoid Complexes

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