α-Phenylthioaldehydes for the effective generation of acyl azolium and azolium enolate intermediates-Reference-Cited by-同舟云学术

α-Phenylthioaldehydes for the effective generation of acyl azolium and azolium enolate intermediates

Published:2024 Issue:24 Volume:15 Page:9369-9375
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ewing Paul M. D. A.¹²,Majhi Pankaj Kumar¹,Prentice Callum¹,Young Claire M.¹,van Rees Karlotta²,Arnold Polly L.³⁴^ORCID,Zysman-Colman Eli¹^ORCID,Smith Andrew D.¹^ORCID

Affiliation:

1. EaStCHEM, School of Chemistry, University of St Andrews, St Andrews, Fife, KY16 9ST, UK

2. EaStCHEM, School of Chemistry, University of Edinburgh, EH9 3JF, UK

3. Dept of Chemistry, University of California, Berkeley, CA, 94720, USA

4. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

Abstract

Readily prepared α-phenylthioaldehydes are introduced as acyl azolium and azolium enolate precursors for a range of NHC-mediated catalytic processes incorporating redox rearrangements, redox esterifications and enantioselective [4 + 2]-cycloadditions.

Funder

HORIZON EUROPE Marie Sklodowska-Curie Actions

Engineering and Physical Sciences Research Council

University of St Andrews

U.S. Department of Energy

Basic Energy Sciences

Chemical Sciences, Geosciences, and Biosciences Division

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06879J

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