Experimental and theoretical investigations on three Dy<sup>III</sup><sub>4</sub> single molecule magnets: structural and magneto-structural correlations-Reference-Cited by-同舟云学术

Experimental and theoretical investigations on three Dy^III₄ single molecule magnets: structural and magneto-structural correlations

Published:2022 Issue:38 Volume:51 Page:14753-14766
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mandal Shuvankar¹,Pramanik Abhishek¹,Dey Sourav²^ORCID,Carrella Luca M.³,Rajaraman Gopalan²^ORCID,Rentschler Eva³^ORCID,Mohanta Sasankasekhar¹^ORCID

Affiliation:

1. Department of Chemistry, University of Calcutta, 92 A. P. C. Road, Kolkata 700 009, India

2. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India

3. Department of Chemistry, Johannes-Gutenberg University Mainz, Duesbergweg 10–14, D-55128 Mainz, Germany

Abstract

The length of the chain of chelating carboxylate influences the deviation from the ideal geometry which, in turn, influences Ueff and τ0 values. Ab initio and DFT calculations provide an in-depth picture of exchange interactions and SMM properties.

Funder

Council of Scientific and Industrial Research, India

Department of Science and Technology, Ministry of Science and Technology, India

Indian Institute of Technology Bombay

Johannes Gutenberg-Universität Mainz

University of Calcutta

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02348B

Reference101 articles.

1. Magnetic bistability in a metal-ion cluster

2. Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level

3. Molecular magnetic hysteresis at 60 kelvin in dysprosocenium

4. Synthesis of 3d Metallic Single-Molecule Magnets

5. Comproportionation Reactions to Manganese(III/IV) Pivalate Clusters: A New Half-Integer Spin Single-Molecule Magnet

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