Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes-Reference-Cited by-同舟云学术

Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes

Published:2018 Issue:15 Volume:20 Page:3432-3435
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Tian Yunfei¹²³⁴⁵,Ling Anbo⁶⁷⁸⁵,Fang Ren⁶⁷⁸⁵,Tan Ren Xiang¹²³⁴⁵,Liu Zhong-Quan¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory Cultivation Base for TCM Quality and Efficacy

2. College of Pharmacy

3. Nanjing University of Chinese Medicine

4. Nanjing 210023

5. China

6. State Key Laboratory of Applied Organic Chemistry

7. Lanzhou University

8. Lanzhou 730000

Abstract

A Cu(ii)-mediated radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes via selective C(sp³)–H bond cleavage was achieved. This reaction features high site-selectivity, diverse functional group tolerance, and scalability.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/GC/C8GC01394B

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3. If CH Bonds Could Talk: Selective CH Bond Oxidation