Superexchange interactions between Fe-3d and Ln-4f states: long range antiferromagnetism in perovskite derivatives Ba3LnFe2O7.5

Author:

Kundu Asish K.12345ORCID,Caignaert Vincent6789,Hardy Vincent6789,Raveau Bernard6789

Affiliation:

1. Discipline of Physics

2. Indian Institute of Information Technology

3. Design & Manufacturing Jabalpur

4. Madhya Pradesh–482005

5. India

6. Laboratoire CRISMAT

7. CNRS ENSICAEN UMR6508

8. Cedex 4

9. France

Abstract

Perovskite derivatives Ba3LnFe2O7.5 can be described as an assemblage of double “FeLn” chains of isolated FeO4 tetrahedrons and YO6 octahedrons, interconnected through dimeric tetrahedral Fe2O7 groups. Long range antiferromagnetic ordering, with TN ranging from 6.2 K for Y to 12.5 K for Dy, is observed in spite of the isolated character of iron.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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