The structural evolution of Mo2C and Mo2C/SiO2 under dry reforming of methane conditions: morphology and support effects-Reference-Cited by-同舟云学术

The structural evolution of Mo₂C and Mo₂C/SiO₂ under dry reforming of methane conditions: morphology and support effects

Published:2022 Issue:18 Volume:12 Page:5620-5628
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Kurlov Alexey¹^ORCID,Stoian Dragos²^ORCID,Baghizadeh Ali³^ORCID,Kountoupi Evgenia¹^ORCID,Deeva Evgeniya B.¹,Willinger Marc³^ORCID,Abdala Paula M.¹^ORCID,Fedorov Alexey¹^ORCID,Müller Christoph R.¹^ORCID

Affiliation:

1. Department of Mechanical and Process Engineering, ETH Zürich, Leonhardstrasse 21, CH 8092 Zürich, Switzerland

2. Swiss-Norwegian Beamlines at the European Synchrotron Radiation Facility, 71 Avenue des Martyrs, Grenoble, France

3. Scientific Center for Optical and Electron Microscopy, ETH Zürich, Auguste-Piccard-Hof 1, CH 8093 Zürich, Switzerland

Abstract

In situ Mo K-edge X-ray absorption spectroscopy reveals different carburization pathways for unsupported and supported MoO3 yielding Mo2C and Mo2C/SiO2. Mo2C/SiO2 features higher resistance to oxidation under dry reforming of methane than Mo2C.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Horizon 2020 Framework Programme

ETH Zürich Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY00729K

Reference36 articles.

1. Catalytic Technology for Carbon Dioxide Reforming of Methane to Synthesis Gas