Preferential solvation ofp-nitroaniline in a binary mixture of chloroform and hydrogen bond acceptor solvents: the role of specific solute–solvent hydrogen bonding

Author:

Malik Prakash Kumar1234,Tripathy Madhusmita1234,Kajjam Aravind Babu1234,Patel Sabita1234ORCID

Affiliation:

1. Department of Chemistry

2. National Institute of Technology

3. Rourkela 769 008

4. India

Abstract

Solute–solvent H-bonding in binary solvent mixtures may increase the local concentration at specific sites resulting in location specific preferential solvation.

Funder

Department of Science and Technology, Ministry of Science and Technology

Board of Research in Nuclear Sciences

National Institute of Technology Rourkela

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference73 articles.

1. C. Reichardt , Solvents and Solvent Effects in Organic Chemistry , 3rd edn, Wiley VCH Verlag GmbH & Co.: KGaA , Weinheim , 2003

2. P. Suppan and N.Ghoneim. , Solvatochromism , 1st edn, Royal Society of Chemistry , Cambridge, U.K. , 1997 , ch. 3

3. What is Solvatochromism?

4. Y. Marcus , Solvent Mixtures: Properties and Selective Solvation , Marcel Dekker, Inc. , New York, Basel , 2002

5. Preferential solvation in two- and in three-component systems

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