Sb3+–doped 0D Cs3GdCl6 microcrystals with a near-unity photoluminescence quantum yield and high thermal quenching resistance for light-emitting application

Author:

Liang Xiantian12,Zhang Wei13,Shi Yitong12,Zhang Wen1,Yang Hongyi1,Huang Ping12,Li Lingyun3ORCID,Zhang Qi3,Zheng Wei12ORCID,Chen Xueyuan12ORCID

Affiliation:

1. Fujian Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, and CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

2. College of Physics and Energy, Fujian Normal University, Fuzhou, Fujian 350117, China

3. Key Laboratory of Advanced Materials Technologies and International (Hongkong, Macao and Taiwan) Joint Laboratory on Advanced Materials Technologies, College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

Abstract

A new class of luminescent materials based on Sb3+–doped 0D Cs3GdCl6 microcrystals featuring a near-unity quantum yield (QY) and good thermal quenching resistance (I150°C = 82.4%) are developed and explored for white light-emitting diodes.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Fujian Province

Publisher

Royal Society of Chemistry (RSC)

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