Ti(Phen)(OC2H5)2Cl2: a highly efficient pre-catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide-Reference-Cited by-同舟云学术

Ti(Phen)(OC2H5)2Cl2: a highly efficient pre-catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide

Published:2017 Issue:70 Volume:7 Page:44259-44264
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wu Rong-Hui¹²³⁴⁵,Wu Jing¹²³⁴,Yu Ming-Xin¹²³⁴,Zhu Long-Guan¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Zhejiang University

3. Hangzhou 310027

4. People's Republic of China

5. Key Laboratory of Chemical Utilization of Forestry Biomass of Zhejiang Province

Abstract

A structurally characterized titanium complex [Ti(Phen)(OC₂H₅)₂Cl₂] (Phen = 1,10-phenanthroline) is reported as a homogeneous pre-catalyst for the selective oxidation of organic sulfides to sulfoxides with a stoichiometric amount H₂O₂ in CH₃OH at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA06883B

Reference64 articles.

1. Improving the solubility of dexlansoprazole by cocrystallization with isonicotinamide

2. The emergence of sulfoxides as efficient ligands in transition metal catalysis

3. Highly efficient selective oxidation of sulfides to sulfoxides by montmorillonite-immobilized metalloporphyrins in the presence of molecular oxygen

4. Solvent free oxidation of sulfides to sulfones by H 2 O 2 in the presence of chromium substituted polyoxometalate as catalyst

5. Sulfoxide-Directed Enantioselective Synthesis of Functionalized Tetrahydropyridines

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