Direct synthesis of doubly deprotonated, dearomatised lutidine PNP Cr and Zr pincer complexes based on isolated K and Li ligand transfer reagents-Reference-Cited by-同舟云学术

Direct synthesis of doubly deprotonated, dearomatised lutidine PNP Cr and Zr pincer complexes based on isolated K and Li ligand transfer reagents

Published:2016 Issue:7 Volume:45 Page:2800-2804
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Simler Thomas¹²³⁴⁵,Frison Gilles⁶⁷⁸⁹¹⁰,Braunstein Pierre¹²³⁴⁵,Danopoulos Andreas A.¹²³⁴⁵

Affiliation:

1. Laboratoire de Chimie de Coordination

2. Institut de Chimie (UMR 7177 CNRS)

3. Université de Strasbourg

4. 67081 Strasbourg

5. France

6. LCM

7. CNRS

8. Ecole polytechnique

9. Université Paris-Saclay

10. 91128 Palaiseau

Abstract

Double deprotonation of a hybrid bis(phosphino)picoline ligand yields lithium or potassium pincer salts with dearomatised lutidine backbones that afford unusual chromium and zirconium complexes by transmetallation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00144K

Reference40 articles.

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4. Transition Metal-Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines

5. Synthesis, Structure, and Reactivity of New Rhodium and Iridium Complexes, Bearing a Highly Electron-Donating PNP System. Iridium-Mediated Vinylic C−H Bond Activation

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