Study of picosecond processes of an intercalated dipyridophenazine Cr(iii) complex bound to defined sequence DNAs using transient absorption and time-resolved infrared methods

Author:

Devereux Stephen J.1234,Keane Páraic M.56789,Vasudevan Suni567,Sazanovich Igor V.1011121314,Towrie Michael1011121314,Cao Qian81516,Sun Xue-Zhong81516,George Michael W.81516,Cardin Christine J.8916,Kane-Maguire Noel A. P.81718,Kelly John M.567,Quinn Susan J.1234

Affiliation:

1. School of Chemistry and Chemical Biology

2. Centre for Synthesis and Chemical Biology

3. University College Dublin

4. Dublin 4, Ireland

5. School of Chemistry

6. Trinity College Dublin

7. Dublin 2, Ireland

8. Department of Chemistry

9. University of Reading

10. Central Laser Facility

11. Research Complex at Harwell

12. Science & Technology Facilities Council

13. Rutherford Appleton Laboratory

14. Didcot, UK

15. University of Nottingham

16. , UK

17. Furman University

18. South Carolina, USA

Abstract

Excited-state quenching of DNA intercalated [Cr(phen)2(dppz)]3+ by guanine proceeds by rapid forward and back electron transfer of <3 ps.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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