Nucleobases tagged to gold nanoclusters cause a mechanistic crossover in the oxidation of CO-Reference-Cited by-同舟云学术

Nucleobases tagged to gold nanoclusters cause a mechanistic crossover in the oxidation of CO

Published:2015 Issue:37 Volume:17 Page:24275-24281
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Rai Sandhya¹²³⁴,Ehara Masahiro⁵⁶⁷⁸,Deva Priyakumar U.¹²³⁴

Affiliation:

1. Center for Computational Natural Sciences and Bioinformatics

2. International Institute of Information Technology

3. Hyderabad

4. India

5. Research Center for Computational Science

6. Institute for Molecular Science

7. Okazaki 444-8585

8. Japan

Abstract

A mechanistic crossover is observed upon using nucleobase tagged gold clusters as catalysts favoring the Eley–Rideal mechanism, over the conventional Langmuir–Hinshelwood pathway followed using pristine gold clusters during CO oxidation.

Funder

Japan Society for the Promotion of Science

National Institutes of Natural Sciences

Council for Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP04273A

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5. CO Oxidation Catalyzed by Supported Gold: Cooperation between Gold and Nanocrystalline Rare-Earth Supports Forms Reactive Surface Superoxide and Peroxide Species

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