Computational study on the mechanism and enantioselectivity of Rh2(S-PTAD)4 catalyzed asymmetric [4+3] cycloaddition between vinylcarbenoids and dienes-Reference-Cited by-同舟云学术

Computational study on the mechanism and enantioselectivity of Rh2(S-PTAD)4 catalyzed asymmetric [4+3] cycloaddition between vinylcarbenoids and dienes

Published:2015 Issue:101 Volume:5 Page:83459-83470
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wang Wan¹²³⁴⁵,Wang Gui-Chang¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Tianjin Key Lab of Metal and Molecule-based Material Chemistry and Synergetic Innovation Center of Chemical Science and Engineering (Tianjin)

3. Nankai University

4. Tianjin 300071

5. P. R. China

Abstract

In this paper, the mechanism of asymmetric [4+3] cycloaddition between a vinylcarbenoid and a diene to form cycloheptadiene has been studied using a two-layer ONIOM methodology consisting of density functional theory and semiempirical PM6.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA14815D

Reference103 articles.

1. Synthetic Studies towards Optically Active 13-Oxyingenol via Asymmetric Cyclopropanation

2. Asymmetric Synthesis of Tropanes by Rhodium-Catalyzed [4 + 3] Cycloaddition

3. Tandem cyclopropanation/cope rearrangement: a general method for the construction of seven-membered rings

4. Efficient Synthesis of Five- and Seven-Membered-Ring Heterocycles by Rhodium(II)-Catalyzed [3+2] and [3+4] Cycloaddition of Diazodicarbonyl Compounds with Conjugated Dienes

5. Catalyst-Controlled Formal [4 + 3] Cycloaddition Applied to the Total Synthesis of (+)-Barekoxide and (−)-Barekol

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