Synthesis, structure and reactivity of cationic rhodium(I) and iridium(I) thioether crowns: structures of [M([9]aneS3)(cod)]+(M = Rh, Ir; cod = cycloocta-1,5-diene) and [Rh([9]aneS3)(C2H4)2]+([9]aneS3= 1,4,7-trithiacyclononane)
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1991/C3/C39910000253
Reference38 articles.
1. Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups
2. Activation of methane by iridium complexes
3. Isotope effects in arene carbon-hydrogen bond activation by [(C5Me5)Rh(PMe3)]
4. Inter- and intramolecular insertion of rhenium into carbon-hydrogen bonds
5. .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds
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