Changes in the SNAr reaction mechanism brought about by preferential solvation-Reference-Cited by-同舟云学术

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Changes in the SNAr reaction mechanism brought about by preferential solvation

Published:2015 Issue:120 Volume:5 Page:99322-99328
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Alarcón-Espósito Jazmín¹²³⁴⁵,Tapia Ricardo A.⁶⁷⁸⁵,Contreras Renato¹²³⁴⁵,Campodónico Paola R.⁹¹⁰¹¹¹²⁸

Affiliation:

1. Departamento de Química

2. Facultad de Ciencias

3. Universidad de Chile

4. Casilla 653-Santiago

5. Chile

6. Facultad de Química

7. Pontificia Universidad Católica de Chile

8. Santiago

9. Centro de Química Médica

10. Facultad de Medicina

11. Clínica Alemana

12. Universidad del Desarrollo

Abstract

For model S_NAr reactions in mixtures of acetonitrile and water, we found preferential solvation in favor of the aqueous phase.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA20779G

Reference43 articles.

1. Ionic Liquids as Designer Solvents for Nucleophilic Aromatic Substitutions

2. Aryl Azides Formation Under Mild Conditions: A Kinetic Study in Some Ionic Liquid Solutions

3. Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2

4. Characterization of solvent mixtures. Part 8 — preferential solvation of chemical probes in binary solvent systems of a polar aprotic hydrogen-bond acceptor solvent with acetonitrile or nitromethane. Solvent effects on aromatic nucleophilic substitution reactions

5. Preferential solvation in two- and in three-component systems

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