Penning spectroscopy and structure of acetylene oligomers in He nanodroplets

Author:

Mandal S.123,Gopal R.453,Shcherbinin M.678,D’Elia A.91011ORCID,Srinivas H.121314,Richter R.151611ORCID,Coreno M.1516111718ORCID,Bapat B.123,Mudrich M.6781920ORCID,Krishnan S. R.19203,Sharma V.21223ORCID

Affiliation:

1. Indian Institute of Science Education and Research

2. Pune 411008

3. India

4. Tata Institute of Fundamental Research

5. Hyderabad 500107

6. Aarhus University

7. 8000 Aarhus C

8. Denmark

9. Department of Physics, University of Trieste

10. 34127 Trieste

11. Italy

12. Max-Planck-Institut für Kernphysik

13. 69117 Heidelberg

14. Germany

15. Elettra-Sincrotrone Trieste

16. 34149 Basovizza

17. Consiglio Nazionale delle Ricerche – Istituto di Struttura della Materia

18. 34149 Trieste

19. Indian Institute of Technology Madras

20. Chennai 600036

21. Indian Institute of Technology Hyderabad

22. Kandi 502285

Abstract

Penning spectroscopy of acetylene molecules dissolved in superfluid He nanodroplets reveals the loosely held molecular aggregate collapsing into a covalently bound oligomer ion upon indirect ionization effected by the photoexcited He* in the host.

Funder

Abdus Salam International Centre for Theoretical Physics

Department of Science and Technology, Ministry of Science and Technology

Max-Planck-Gesellschaft

Carlsbergfondet

Ministry of Human Resource Development

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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