Motional freedom of dimethylammonium ions in a cyanoelpasolite, [(CH3)2NH2]2KCo(CN)6, which exhibits phase transition associated with a distinct change in dielectric property-Reference-Cited by-同舟云学术

Motional freedom of dimethylammonium ions in a cyanoelpasolite, [(CH3)2NH2]2KCo(CN)6, which exhibits phase transition associated with a distinct change in dielectric property

Published:2020 Issue:17 Volume:22 Page:9301-9307
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Asaji Tetsuo¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. College of Humanities and Sciences

3. Nihon University

4. Tokyo 156-8550

5. Japan

Abstract

Although the phase transition of (DMA)₂KCo(CN)₆ has been reported as an isosymmetric transition, ¹⁴N NQR spectra showed a lowering of crystal symmetry.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP00680G

Reference21 articles.

1. Tunable dielectric transitions in layered organic–inorganic hybrid perovskite-type compounds: [NH3(CH2)2Cl]2[CdCl4−4xBr4x] (x = 0, 1/4, 1)

2. Molecular Electronics

3. Structural phase transition-associated dielectric transition and ferroelectricity in coordination compounds

4. Tunable and Switchable Dielectric Constant in an Amphidynamic Crystal

5. Dynamics of a caged imidazolium cation–toward understanding the order-disorder phase transition and the switchable dielectric constant

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