Substituted aromatic pentaphosphole ligands – a journey across the p-block

Author:

Riesinger Christoph1,Balázs Gábor1,Seidl Michael1,Scheer Manfred1ORCID

Affiliation:

1. Institute of Inorganic Chemistry, University of Regensburg, 93040 Regensburg, Germany

Abstract

The reactivity of cationic electrophiles towards pentaphosphaferrocene [Cp*Fe(ƞ5-P5)] is explored. We report P–E bond formation for electrophiles across the p-block, producing coordination complexes with unprecedented hetero-bispentaphosphole and hetero-pentaphosphole ligands.

Funder

Deutsche Forschungsgemeinschaft

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference105 articles.

1. R.Brückner , Reaktionsmechanismen , Springer , Berlin, Heidelberg , 2004 , pp. 203–235

2. P. Y.Bruice , Organische Chemie , Pearson Studium , Hallbergmoos , 2013 , pp. 627–642

3. A New Type of Organo-Iron Compound

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