Dirhodium(<scp>ii</scp>) complex catalyzed dehydrosilylation of styrenes: theoretical investigations on the mechanism, selectivity, and ligand effects-Reference-Cited by-同舟云学术

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Dirhodium(ii) complex catalyzed dehydrosilylation of styrenes: theoretical investigations on the mechanism, selectivity, and ligand effects

Published:2024 Issue: Volume: Page:
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhong Ziying¹,Li Qingzhong²^ORCID,Li Xiaoyan¹^ORCID

Affiliation:

1. College of Chemistry and Material Science, Hebei Key Laboratory of Inorganic and Nano-Materials, National Demonstration Center for Experimental Chemistry, Hebei Normal University, Shijiazhuang, 050024, P. R. China

2. The Laboratory of Theoretical and Computational Chemistry, College of Chemistry& Chemical Engineering, Yantai University, Yantai, 264005, China

Abstract

The structure of the actual catalyst and the detailed mechanism of the dehydrogenation of vinylarene catalyzed by a dirhodium(ii) complex are determined via DFT calculations.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP02576H

Reference74 articles.

1. 1946 and the Early History of Hydrosilylation

2. Efficient Routes to Carbon–Silicon Bond Formation for the Synthesis of Silicon-Containing Peptides and Azasilaheterocycles

3. Silicon-based cross-coupling reaction: an environmentally benign version

4. Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

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