The influence of large-amplitude librational motion on the hydrogen bond energy for alcohol

The influence of large-amplitude librational motion on the hydrogen bond energy for alcohol–water complexes

Published:2015 Issue:37 Volume:17 Page:23761-23769
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Andersen J.¹²³⁴,Heimdal J.⁵⁶⁷⁸,Wugt Larsen R.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Technical University of Denmark

3. 2800 Kgs. Lyngby

4. Denmark

5. MAX-IV Laboratory

6. Lund University

7. 22100 Lund

8. Sweden

Abstract

The intermolecular large-amplitude OH librational modes for mixed hydrogen-bonded complexes of water with methanol and t-butanol are unambiguously assigned for the first time.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP04321B

Reference43 articles.

1. The structural properties of alcohol–water mixtures

2. Thermochemical Investigations of the Water-Ethanol and Water-Methanol Solvent Systems. I. Heats of Mixing, Heats of Solution, and Heats of Ionization of Water

3. Thermodynamic properties of aqueous non-electrolyte mixtures I. Excess enthalpy for water + ethanol at 298.15 to 383.15 K

4. Excess volumes and excess heat capacities of water + ethanol at 298.15 K

5. Thermodynamics of aqueous mixtures of nonelectrolytes. I. Excess volumes of water-n-alcohol mixtures at several temperatures

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