Non-covalent assembly of proton donors and p-benzoquinone anions for co-electrocatalytic reduction of dioxygen-Reference-Cited by-同舟云学术

Non-covalent assembly of proton donors and p-benzoquinone anions for co-electrocatalytic reduction of dioxygen

Published:2021 Issue:28 Volume:12 Page:9733-9741
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hooe Shelby L.¹²³⁴^ORCID,Cook Emma N.¹²³⁴^ORCID,Reid Amelia G.¹²³⁴^ORCID,Machan Charles W.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Virginia

3. Charlottesville

4. USA

Abstract

Non-covalent interactions between reduced p-benzoquinone species and weak acids stabilize intermediates which can switch dioxygen reduction selectivity from H₂O₂ to H₂O for a molecular Mn catalyst.

Funder

American Chemical Society Petroleum Research Fund

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01271A

Reference55 articles.

1. Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

2. Proton Relays in Molecular Catalysis of Electrochemical Reactions: Origin and Limitations of the Boosting Effect

3. Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

4. Water-Splitting Chemistry of Photosystem II

5. COOPERATION OF CHARGES IN PHOTOSYNTHETIC O2EVOLUTION–I. A LINEAR FOUR STEP MECHANISM

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