3D-Frameworks and 2D-networks of lanthanide coordination polymers with 3-pyridylpyrazole: photophysical and magnetic properties

Author:

Youssef Heba12,Schäfer Thomas1,Becker Jonathan1,Sedykh Alexander E.1ORCID,Basso Leonardo1,Pietzonka Clemens3,Taydakov Ilya V.4ORCID,Kraus Florian3,Müller-Buschbaum Klaus15ORCID

Affiliation:

1. Institute of Inorganic and Analytical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, 35392 Giessen, Germany

2. Department of Chemistry, Faculty of Science, Mansoura University, El Gomhouria, Mansoura Qism 2, Dakahlia Governorate, 11432, Mansoura, Egypt

3. Fachbereich Chemie, Philipps-Universitaet Marburg, Hans-Meerwein-Straße, 35032 Marburg, Germany

4. Lebedev Physical Institute of the Russian Academy of Sciences, Leninskiy pr-t, 53, 119991, Moscow, Russia

5. Center for Materials Research (LAMA), Justus-Liebig-University Giessen, Heinrich-Buff-Ring 16, 35392 Giessen, Germany

Abstract

Reactions of anhydrous lanthanide chlorides with 3-(3-pyridyl)pyrazole result in fifteen 3D- and 2D-coordination polymers besides salt-like complexes that differ in constitution and structural extension and show versatile photophysical, thermal, and magnetic properties.

Funder

Volkswagen Foundation

Ministry of Higher Education

Deutscher Akademischer Austauschdienst

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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