NHC-coordinated silagermenylidene functionalized in allylic position and its behaviour as a ligand
Author:
Affiliation:
1. Krupp-Chair of General and Inorganic Chemistry
2. Saarland University
3. 66125 Saarbrücken, Germany
Abstract
Through coordination by an N-heterocyclic carbene (NHC) silagermenylidene (Tip2Cl)Si-(Tip)SiGe·NHCiPr2Me2 (4-E/Z; Tip = 2,4,6-iPr3C6H2; NHCiPr2Me2 = 1,3-iPr2-4,5-Me2imidazol-2-ylidene) is available as an E/Z-equilibrium mixture from Tip2SiSi(Tip)Li and NHCiPr2Me2·GeCl2.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00094C
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