Synthesis, dynamics and redox properties of eight-coordinate zirconium catecholate complexes
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. University of Notre Dame
3. Notre Dame
4. USA
Abstract
Eight-coordinate zirconium complexes of a chelating bis(iminium-catecholate) ligand can be reversibly oxidized to semiquinone complexes.
Funder
Arthur J. Schmitt Foundation
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02487B
Reference44 articles.
1. Studies on charge distribution and valence tautomerism in transition metal complexes of catecholate and semiquinonate ligands
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3. “Oxidative Addition” to a Zirconium(IV) Redox-Active Ligand Complex
4. Group IV Imino-Semiquinone Complexes Obtained by Oxidative Addition of Halogens
5. On the border between localization and delocalization: tris(iminoxolene)titanium(iv)
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