Regioselective B2–6 penta-iodination of the [CB11H12] monocarborane cluster by palladium catalysis

Author:

Lin Chuhao1,Jin Yujie1,Sun Jizeng1,Ye Zehua1,Chen Tao1,Liu Jiyong1,Duttwyler Simon1ORCID

Affiliation:

1. Department of Chemistry, Zhejiang University, 866 Yuhangtang Road, 310058 Hangzhou, China

Abstract

Palladium-catalyzed penta-iodination/decarboxylation of the B2–6 positions of the monocarborane cage provides novel derivatives in a single step.

Funder

Zhejiang University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference52 articles.

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2. R. N.Grimes , Carboranes , Elsevier , London , 3rd edn, 2016

3. Handbook of Boron Science: With Applications in Organometallics Catalysis, Materials and Medicine , ed. N. S. Hosmane and R. Eagling , World Scientific Publishing , London , 2018

4. Update 1 of:Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12–

5. Transition metal complexes with carboranylphosphine ligands

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