Solution and solid-state characterization of rare silyluranium(<scp>iii</scp>) complexes-Reference-Cited by-同舟云学术

Solution and solid-state characterization of rare silyluranium(iii) complexes

Published:2024 Issue:29 Volume:60 Page:3954-3957
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lin Nathan J.¹^ORCID,Zeller Matthias¹,Bart Suzanne C.¹^ORCID

Affiliation:

1. H. C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA

Abstract

A uranium(iii) silylate complex [K(DME)4]-[UI2{(Si(SiMe3)2SiMe2)2O}] (1) was stabilized by the addition of 18-crown-6 to form [K(18-crown-6)][UI2{(Si(SiMe3)2SiMe2)2O}]. This species was fully characterized using multinuclear NMR spectroscopy, electronic absorption spectroscopy and X-ray crystallography.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00655K

Reference31 articles.

1. Mineralogy, Crystallography and Structural Complexity of Natural Uranyl Silicates

2. Fixation of radioactive waste in high silica glasses

3. Uranium Retention in Silica-Rich Natural Glasses: Nuclear Waste Disposal Aspect

4. Source Analysis of Silicon and Uranium in uranium-rich shale in the Xiuwu Basin, Southern China

5. Organoactinides in catalysis

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