Chromous carbonates containing a square-grid layer of {Cr2(CO3)4}n4n− based on a dichromium(ii,ii) paddlewheel core-Reference-Cited by-同舟云学术

Chromous carbonates containing a square-grid layer of {Cr2(CO3)4}n4n− based on a dichromium(ii,ii) paddlewheel core

Published:2021 Issue:7 Volume:50 Page:2387-2392
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dong Zhi-Qiang¹²³⁴⁵^ORCID,Yang Jian-Hui¹²³⁴⁵^ORCID,Liu Bin¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education

2. Shaanxi Key Laboratory of Physico-Inorganic Chemistry

3. College of Chemistry and Materials Science

4. Northwest University

5. Xi'an 710127

Abstract

The structural, spectroscopic and magnetic properties of chromous carbonates with a square-grid layer structure constructed from Cr₂(CO₃)₄⁴⁻ paddlewheel units.

Funder

Natural Science Foundation of Shaanxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04160B

Reference47 articles.

1. Multiple chromium(II)-chromium(II) and rhodium(II)-rhodium(II) bonds

2. The crystal and molecular structures of dichromium tetraacetate dihydrate and dirhodium tetraacetate dihydrate

3. Applications of High-Field (W-Band) EPR to M−M Bonded Units (M = Cr, Mo): The First Confirmed Oxidation of a Cr24+ Paddlewheel Complex to a Stable Isostructural Cr25+ Product

4. A New Example of a Dichromium Compound with a Supershort CrCr Quadruple Bond

5. Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers

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