Kinetic analysis of the asymmetric hydrogenation of (E)-2,3-diphenylpropenoic acid over cinchonidine derivative-modified Pd/C: quinoline ring modification
Author:
Affiliation:
1. Graduate School of Material Science
2. University of Hyogo
3. Japan
Abstract
The substitutions at the 2′- and/or 6′-positions of the quinoline ring of cinchonidine reduce both the intrinsic enantioselectivity and adsorption strength for the enantioselective hydrogenation of α-phenylcinnamic acid over Pd/C.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY01380C
Reference69 articles.
1. Recent Progress in Heterogeneous Asymmetric Hydrogenation of C═O and C═C Bonds on Supported Noble Metal Catalysts
2. Crucial aspects in the design of chirally modified noble metal catalysts for asymmetric hydrogenation of activated ketones
3. Heterogeneous asymmetric hydrogenation over chiral molecule-modified metal particles
4. Unexpected Inversions in Asymmetric Reactions: Reactions with Chiral Metal Complexes, Chiral Organocatalysts, and Heterogeneous Chiral Catalysts
5. Chiral Modification of Solid Surfaces: A Molecular View
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