Equatorial ligand plane perturbations lead to a spin-state change in an iron(iii) porphyrin dimer-Reference-Cited by-同舟云学术

Equatorial ligand plane perturbations lead to a spin-state change in an iron(iii) porphyrin dimer

Published:2019 Issue:19 Volume:48 Page:6353-6357
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Khan Firoz Shah Tuglak¹²³⁴,Shah Syed Jehanger¹²³⁴,Bhowmik Susovan¹²³⁴,Reinhard Fabián G. Cantú⁵⁶⁷⁸^ORCID,Sainna Mala A.⁵⁶⁷⁸^ORCID,de Visser Sam P.⁵⁶⁷⁸^ORCID,Rath Sankar Prasad¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. Kanpur-208016

4. India

5. The Manchester Institute of Biotechnology and the School of Chemical Engineering and Analytical Science

6. The University of Manchester

7. Manchester M1 7DN

8. UK

Abstract

A complete reversal of the spin state of iron(iii) is observed upon a small change to the diporphyrin bridge from ethane to ethene by keeping all other factors intact.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Consejo Nacional de Ciencia y Tecnología

Petroleum Technology Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01182J

Reference59 articles.

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2. Spin-state/stereochemical relationships in iron porphyrins: implications for the hemoproteins

3. Conformational control of cofactors in nature – the influence of protein-induced macrocycle distortion on the biological function of tetrapyrroles

4. Computational Quantification of the Physicochemical Effects of Heme Distortion: Redox Control in the Reaction Center Cytochrome Subunit of Blastochloris viridis

5. Nonplanar porphyrins and their significance in proteins

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