A reactivity model for oxidative addition to palladium enables quantitative predictions for catalytic cross-coupling reactions-Reference-Cited by-同舟云学术

A reactivity model for oxidative addition to palladium enables quantitative predictions for catalytic cross-coupling reactions

Published:2022 Issue:12 Volume:13 Page:3477-3488
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lu Jingru¹,Donnecke Sofia¹,Paci Irina¹^ORCID,Leitch David C.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Victoria, 3800 Finnerty Rd, Victoria BC, V8P 5C2, Canada

Abstract

We report a quantitative model for oxidative addition reactivity in palladium-catalyzed cross-coupling, which is broadly applicable to predict reactivity and selectivity for complex substrates from simple molecular descriptors.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00174H

Reference83 articles.

1. Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future

2. Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

3. Organometallic palladium reagents for cysteine bioconjugation

4. Pd-Catalyzed Cross Coupling Strategy for Functional Porphyrin Arrays

5. Chemistry informer libraries: a chemoinformatics enabled approach to evaluate and advance synthetic methods

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