Potassium-rich antiperovskites K<sub>3</sub>HTe and K<sub>3</sub>FTe and their structural relation to lithium and sodium counterparts-Reference-Cited by-同舟云学术

Potassium-rich antiperovskites K₃HTe and K₃FTe and their structural relation to lithium and sodium counterparts

Published:2023 Issue:26 Volume:52 Page:9026-9031
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Okada Koji¹^ORCID,Fujii Susumu²³^ORCID,Tassel Cédric¹,Gao Shenghan¹,Ubukata Hiroki¹^ORCID,Pan Wenli⁴,Yamamoto Kentaro⁴⁵^ORCID,Uchimoto Yoshiharu⁴^ORCID,Kuwabara Akihide²^ORCID,Kageyama Hiroshi¹^ORCID

Affiliation:

1. Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

2. Nanostructures Research Laboratory, Japan Fine Ceramics Center, Nagoya 456-8587, Japan

3. Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan

4. Graduate School of Human and Environment Studies, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan

5. Faculty of Engineering, Nara Women's University, Kitauoyanishimachi, Nara 630-8506, Japan

Abstract

Unlike perovskite oxides, antiperovskites M3HCh and M3FCh (M = Li, Na; Ch = S, Se, Te) mostly retain their ideal cubic structure owing to anionic size flexibility and low-energy phonon modes that promote their ionic conductivity.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01039B

Reference39 articles.

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2. Antiperovskite Li3OCl Superionic Conductor Films for Solid-State Li-Ion Batteries

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4. The Ag/Ag3SI/I2 solid-electrolyte cell

5. Giant magnetoresistance in the intermetallic compoundMn3GaC