Metal-free direct difunctionalization of alkenes with I2O5 and P(O)–H compounds leading to β-iodophosphates

Author:

Liu Chunli12345,Zhu Minghui12345,Wei Wei12345,Yang Daoshan12345,Cui Hong12345,Liu Xiaoxia12345,Wang Hua12345

Affiliation:

1. The Key Laboratory of Life-Organic Analysis and Key Laboratory of Pharmaceutical Intermediates and Analysis of Natural Medicine

2. School of Chemistry and Chemical Engineering

3. Qufu Normal University

4. Qufu 273165

5. China

Abstract

A novel and efficient procedure for direct difunctionalization of alkenes with I2O5 and P(O)–H compounds has been developed under metal-free conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference97 articles.

1. P. A. Sibbald , Palladium-catalyzed oxidative difunctionalization of alkenes: New reactivity and new mechanisms, ProQuest UMI Dissertation Publishing, Ann Arbor, MI, 2011

2. B. Jacques and K.Muinz, in Catalyzed carbon-heteroatom bond formation, ed. A. K. Yudin, Wiley, VCH, Weinheim, Germany, 2011

3. Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

4. Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

5. Pd(II)-Catalyzed Intermolecular 1,2-Diamination of Conjugated Dienes

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