Luminescent (metallo-supramolecular) cross-linked lanthanide hydrogels from a btp (2,3-bis(1,2,3-triazol-4-yl)picolinamide) monomer give rise to strong Tb(iii) and Eu(iii) centred emissions

Author:

Hegarty Isabel N.1,Bradberry Samuel J.1,Lovitt June I.1,Delente Jason M.12,Willis-Fox Niamh3,Daly Ronan3,Gunnlaugsson Thorfinnur12ORCID

Affiliation:

1. School of Chemistry and Trinity Biomedical Sciences Institute, The University of Dublin, Trinity College Dublin, Dublin 2, Ireland

2. AMBER (Advanced Materials and Bioengineering Research) Centre, Trinity College Dublin, The University of Dublin, Dublin 2, Ireland

3. Institute for Manufacturing, Department of Engineering, University of Cambridge, 17 Charles Babbage Road, Cambridge, CB3 0FS, UK

Abstract

The synthesis and study of the lanthanide luminescent 2,3-bis(1,2,3- triazol-4-yl)picolinamide (btp) based hydrogels F1 and F2 is described where Tb(iii) or Eu(iii) are also used to crosslink the btp units within the polymers.

Funder

Science Foundation Ireland

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

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