Ligand symmetry significantly affects spin crossover behaviour in isomeric [Fe(pybox)2]2+ complexes-Reference-Cited by-同舟云学术

Ligand symmetry significantly affects spin crossover behaviour in isomeric [Fe(pybox)2]2+ complexes

Published:2021 Issue:9 Volume:50 Page:3369-3378
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Run-Guo¹²³⁴⁵^ORCID,Meng Yin-Shan⁶⁷⁸⁵^ORCID,Gao Fang-Fang⁹¹⁰¹¹¹²¹³,Gao Wan-Qing¹²³⁴⁵,Liu Chun-Hua¹²³⁴⁵,Li Anyang⁹¹⁰¹¹¹²¹³^ORCID,Liu Tao⁶⁷⁸⁵^ORCID,Zhu Yuan-Yuan¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering

3. Hefei University of Technology

4. Hefei 230009

5. China

6. State Key Laboratory of Fine Chemicals

7. Dalian University of Technology

8. Dalian 116024

9. Key Laboratory of Synthetic and Natural Functional Molecule of Ministry of Education

10. College of Chemistry and Materials Science

11. Northwest University

12. Xi'an

13. P. R. China

Abstract

We demonstrate that ligand symmetry imposes strong influence on spin crossover behaviour in three [Fe(pybox)₂]²⁺ isomers bearing phenyl substituents.

Funder

National Natural Science Foundation of China

Dalian University of Technology

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03978K

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4. Structure:function relationships in molecular spin-crossover complexes

5. A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

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