Catalytic activation of remote alkenes through silyl-rhodium(iii) complexes

Author:

Prieto-Pascual Unai1,Martínez de Morentin Aitor1,Choquesillo-Lazarte Duane2ORCID,Rodríguez-Diéguez Antonio3ORCID,Freixa Zoraida14ORCID,Huertos Miguel A.14ORCID

Affiliation:

1. Facultad de Química, Universidad del País Vasco (UPV/EHU), 20018, San Sebastián, Spain

2. Laboratorio de Estudios Cristalográficos, IACT, CSIC-UGR, 18071, Granada, Spain

3. Dpto. Química Inorgánica, Universidad de Granada, 18071, Granada, Spain

4. IKERBASQUE, Basque Fundation for Science, 48011, Bilbao, Spain

Abstract

Rhodium(iii) complexes, bearing silyl-nitrogen ligands, as catalysts for the tandem isomerization–hydrosilylation reaction.

Funder

Eusko Jaurlaritza

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference41 articles.

1. I.Flemin , in Comprehensive Organic Chemistry II , ed. D. Burton and W. D. Ollis , Pergamon Press , Oxford, UK , 1979 , p. 577

2. B.Marciniec , Applied Homogeneus Catalysis with Organometallic Compounds , Weinheim, Germany , 1996

3. D. R.Thomas , in Comprehensive Organometallic Chemistry , ed. W. W. Abel , F. G. A. Stone and G. Wilkinson , Pergamon Press , Oxford, UK , 1995 , p. 114

4. J. L.Speier , in Advances in Organometallic Chemistry , ed. F. G. A. Stone and W. Robert , Academic Press , 1979 , vol. 17 , p. 407

5. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts

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