Microstructure-driven annihilation effects and dispersive excited state dynamics in solid-state films of a model sensitizer for photon energy up-conversion applications-Reference-Cited by-同舟云学术

Microstructure-driven annihilation effects and dispersive excited state dynamics in solid-state films of a model sensitizer for photon energy up-conversion applications

Published:2023 Issue:8 Volume:14 Page:2009-2023
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Goudarzi Hossein¹,Koutsokeras Loukas²,Balawi Ahmed H.³,Sun Chen⁴,Manolis Giorgos K.⁵,Gasparini Nicola³⁶^ORCID,Peisen Yuan²,Antoniou Giannis²^ORCID,Athanasopoulos Stavros⁷^ORCID,Tselios Charalampos C.⁸^ORCID,Falaras Polycarpos⁵^ORCID,Varotsis Constantinos⁸,Laquai Frédéric³^ORCID,Cabanillas-González Juan⁴^ORCID,Keivanidis Panagiotis E.²^ORCID

Affiliation:

1. Centre for Nano Science and Technology @PoliMi, Fondazione Istituto Italiano di Tecnologia, 20133 Milano, Italy

2. Device Technology and Chemical Physics Laboratory, Department of Mechanical Engineering and Materials Science and Engineering, Cyprus University of Technology, 3041 Limassol, Cyprus

3. King Abdullah University of Science and Technology (KAUST), KAUST Solar Center (KSC), Physical Sciences and Engineering Division (PSE), 23955-6900 Thuwal, Kingdom of Saudi Arabia

4. IMDEA Nanoscience, Ciudad Universitaria de Cantoblanco, Calle Faraday 9, ES 28049 Madrid, Spain

5. Institute of Nanoscience and Nanotechnology, NCSR “Demokritos”, 15341 Agia Paraskevi, Athens, Greece

6. Department of Chemistry, Centre for Processable Electronics, Imperial College London, W120BZ, UK

7. Departamento de Física, Universidad Carlos III de Madrid, 28911 Leganés, Madrid, Spain

8. Environmental Biocatalysis and Biotechnology Laboratory, Department of Chemical Engineering, Cyprus University of Technology, 3603 Limassol, Cyprus

Abstract

Dispersive diffusion and annihilation of excitations in the amorphous aggregate phase of a square-planar PtOEP sensitizer in the solid state result in the activation of delayed PtOEP fluorescence through an up-converted PtII-centered state.

Funder

Ministerio de Ciencia, Innovación y Universidades

Ministerio de Ciencia e Innovación

King Abdullah University of Science and Technology

Deutsche Forschungsgemeinschaft

China Scholarship Council

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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