Photoanodes for water oxidation with visible light based on a pentacyclic quinoid organic dye enabling proton-coupled electron transfer

Author:

Volpato Giulia Alice1234ORCID,Marasi Martina12345ORCID,Gobbato Thomas1234ORCID,Valentini Francesca5674ORCID,Sabuzi Federica5674ORCID,Gagliardi Valeria12345ORCID,Bonetto Alessandro8910114ORCID,Marcomini Antonio8910114ORCID,Berardi Serena1213144ORCID,Conte Valeria5674ORCID,Bonchio Marcella1234ORCID,Caramori Stefano1213144ORCID,Galloni Pierluca5674ORCID,Sartorel Andrea1234ORCID

Affiliation:

1. Department of Chemical Sciences

2. University of Padova

3. 35131 Padova

4. Italy

5. Department of Chemical Science and Technologies

6. University of Rome “Tor Vergata”

7. snc 00133 Roma

8. Department of Environmental Sciences

9. Informatics and Statistics

10. University Ca' Foscari Venice

11. 30175 Marghera

12. Department of Chemical and Pharmaceutical Sciences

13. University of Ferrara, and Centro Interuniversitario per la Conversione Chimica dell'Energia Solare (SolarChem)

14. 44121 Ferrara

Abstract

A novel pentacyclic quinoid photosensitizer with extended absorption in the visible region and enabling proton-coupled electron transfer is employed in photoelectrodes for water oxidation in combination with a ruthenium polyoxometalate catalyst.

Funder

Università degli Studi di Padova

Fondazione Cassa di Risparmio di Padova e Rovigo

Regione Lazio

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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