Unexpected and frustrating transformations of double-decker silsesquioxanes-Reference-Cited by-同舟云学术

Unexpected and frustrating transformations of double-decker silsesquioxanes

Published:2022 Issue:2 Volume:9 Page:379-390
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Rzonsowska Monika¹²,Mituła Katarzyna¹²,Duszczak Julia¹²,Kasperkowiak Małgorzata²,Januszewski Rafał²³^ORCID,Grześkiewicz Anita¹,Kubicki Maciej¹^ORCID,Głowacka Daria¹,Dudziec Beata¹²^ORCID

Affiliation:

1. Faculty of Chemistry, Adam Mickiewicz University in Poznan, Uniwersytetu Poznanskiego 8, 61-614 Poznan, Poland

2. Centre for Advanced Technologies, Adam Mickiewicz University in Poznan, Uniwersytetu Poznanskiego 10, 61-614 Poznan, Poland

3. Department of Chemistry and Technology of Silicon Compounds, Faculty of Chemistry, Adam Mickiewicz University in Poznan, Uniwersytetu Poznanskiego 8, 61-614 Poznan, Poland

Abstract

This paper outlines an unexpected type of intramolecular transformation of DDSQ during hydrolytic condensation and surprising catalytic reactivity in silylative coupling.

Funder

Narodowe Centrum Nauki

Narodowe Centrum Badań i Rozwoju

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D1QI01363G

Reference65 articles.

1. Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes

2. Cage-like silsesquioxanes-based hybrid materials