On the rearrangements of biologically-relevant vinyl allene oxides to cis-cyclopentenones, ketols, and Favorskii-type carboxylic acids-Reference-Cited by-同舟云学术

On the rearrangements of biologically-relevant vinyl allene oxides to cis-cyclopentenones, ketols, and Favorskii-type carboxylic acids

Published:2021 Issue:43 Volume:19 Page:9460-9469
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Villar Pedro¹^ORCID,Grechkin Alexander N.²,González-Pérez Adán B.¹,de Lera Ángel R.¹^ORCID

Affiliation:

1. Departamento de Química Orgánica, Facultade de Química, Universidade de Vigo, CINBIO, As Lagoas-Marcosende, 36310 Vigo, Spain

2. Kazan Institute of Biochemistry and Biophysics, FRC Kazan Scientific Center of Russian Academy of Sciences, P.O. Box 261, 420111 Kazan, Russia

Abstract

The intriguing rearrangement of naturally occurring vinyl allene oxides to ketols, cyclopropylcarbinols and Favorskii-type carboxylic acids has been computational justified with model systems.

Funder

Ministerio de Economía y Competitividad

Xunta de Galicia

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01847G

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4. Formation of an allene oxide from (8R)-8-hydroperoxyeicosatetraenoic acid in the coral Plexaura homomalla

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