Copper-catalyzed synthesis of benzo[d][1,3]dioxin-4-ones via tandem Ar–halogen bond hydroxylation and dichloromethane-based double Williamson etherification
Author:
Affiliation:
1. College of Chemistry and Chemical Engineering
2. Jiangxi Normal University
3. Nanchang 330022
4. P. R. China
Abstract
The copper-catalyzed tandem reactions of o-halobenzoic acids, dichloromethane and KOH giving benzo[d][1,3]dioxin-4-ones via tandem Ar–X hydroxylation and double Williamson etherification are reported.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ00180K
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1. Renaissance of Ullmann and Goldberg Reactions - Progress in Copper Catalyzed C-N-, C-O- and C-S-Coupling
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4. Palladium-Catalyzed Coupling of Ammonia and Hydroxide with Aryl Halides: The Direct Synthesis of Primary Anilines and Phenols
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