Hydrothermally stable Ru/HZSM-5-catalyzed selective hydrogenolysis of lignin-derived substituted phenols to bio-arenes in water

Author:

Luo Zhicheng12345,Zheng Zhaoxia12345,Wang Yuechao678910,Sun Geng678910,Jiang Hong678910,Zhao Chen12345

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes

2. School of Chemistry and Molecular Engineering

3. East China Normal University

4. Shanghai

5. China

6. Beijing National Laboratory for Molecular Sciences

7. State Key Laboratory of Rare Earth Materials Chemistry and Applications

8. College of Chemistry and Molecular Engineering

9. Peking University

10. Beijing 100871

Abstract

In the context of arenes generated from bioresources, a hydrothermally stable catalyst Ru/HZSM-5 is reported for the quantitative conversion of lignin-derived phenol, anisole, guaiacols, and syringols into bioaromatic hydrocarbons in a one-pot aqueous-phase process in moderate conditions (240 °C, 2 bar H2), with a high carbon balance of 98.6%.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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