Stereoselective allylic reduction via one-pot palladium-catalyzed allylic sulfonation and sulfinyl retro-ene reactions-Reference-Cited by-同舟云学术

Stereoselective allylic reduction via one-pot palladium-catalyzed allylic sulfonation and sulfinyl retro-ene reactions

Published:2018 Issue:14 Volume:5 Page:2158-2162
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Um Hyun-Suk¹²³⁴,Min Jungki¹²³⁴,An Taeyang¹²³⁴,Choi Jin⁵⁶⁷⁴,Lee Chulbom¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Seoul National University

3. Seoul 08826

4. South Korea

5. Medicinal Chemistry Laboratory

6. Chong Kun Dang Research Institute

7. Yongin 16995

Abstract

A tandem approach for the stereoselective allylic reduction has been developed based on a strategy combining the palladium-catalyzed S-allylation and the sulfinyl retro-ene reactions.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00233A

Reference42 articles.

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2. Organopalladium intermediates in organic synthesis

3. Asymmetric Transition Metal-Catalyzed Allylic Alkylations

4. Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis

5. Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

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