Z-shaped polycyclic aromatic hydrocarbons with embedded five-membered rings and their application in organic thin-film transistors

Author:

Elbert Sven M.1,Bolgert Evelin1,Paine Owen T. A.1,Ghalami Farhad2,Zhang Wen-Shan1ORCID,Zschieschang Ute3,Rominger Frank1,Popp Dennis1,Klauk Hagen3ORCID,Elstner Marcus2ORCID,Mastalerz Michael1ORCID

Affiliation:

1. Institute of Organic Chemistry, Ruprecht-Karls-Universtity Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany

2. Institute of Physical Chemistry and Theoretical Chemical Chemistry, Karlsruhe Institute of Technology, Kaiserstraße 12, D-76131, Karlsruhe, Germany

3. Max Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, Germany

Abstract

Z-shaped polycyclic hydrocarbons with embedded five-membered rings as well as their diaza-analogues have been synthesized and showed charge carrier mobilities up to 0.4 cm2 V−1 s−1 in organic p-channel thin-film transistors.

Funder

Deutsche Forschungsgemeinschaft

Baden-Württemberg Stiftung

Publisher

Royal Society of Chemistry (RSC)

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