Enhanced CO2 sorption properties in a polarizable [WO2F4]2−-pillared physisorbent under direct air capture conditions

Author:

O’Nolan Daniel1ORCID,Chatterton Lindsey1,Bellamy Timothy1,Ennis J. Todd1,Soukri Mustapha1ORCID

Affiliation:

1. RTI International, P.O. Box 12194, Research Triangle Park, NC 27709, USA

Abstract

We report an oxyfluoride-based ultramicroporous metal–organic framework [Ni(WO2F4)-(pyrazine)2] with enhanced trace CO2 sorption performance (0.685 mmolCO2 gsorbent−1 at 75%RH) and stability under Direct Air Capture conditions.

Funder

Office of Fossil Energy and Carbon Management

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference30 articles.

1. Inside-Out: Driving Down Direct Air Capture Costs With High-Efficiency Adsorbents

2. Committee on Developing a Research Agenda for Carbon Dioxide Removal and Reliable Sequestration, Board on Atmospheric Sciences and Climate, Board on Energy and Environmental Systems, Board on Agriculture and Natural Resources, Board on Earth Sciences and Resources, Board on Chemical Sciences and Technology, Ocean Studies Board, Division on Earth and Life Studies, and National Academies of Sciences, Engineering, and Medicine, Negative Emissions Technologies and Reliable Sequestration: A Research Agenda , National Academies Press , Washington, D.C. , 2019

3. The Chemistry and Applications of Metal-Organic Frameworks

4. Porous materials with pre-designed single-molecule traps for CO2 selective adsorption

5. Metal–organic framework materials , ed. L. R. MacGillivray and C. M. Lukehart , Wiley , Chichester, West Sussex , 2014

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