CO oxidation over a ligand coordinated single site Rh catalyst: identification of the active complex-Reference-Cited by-同舟云学术

CO oxidation over a ligand coordinated single site Rh catalyst: identification of the active complex

Published:2024 Issue: Volume: Page:
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Rezvani Fereshteh¹^ORCID,Zhou Xuemei¹²^ORCID,Meira Debora Motta³,Sterbinsky George E.⁴,Tait Steven L.¹^ORCID

Affiliation:

1. Department of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, Indiana 47405, USA

2. School of Chemical Engineering, Sichuan University, No. 24 South Section 1, Yihuan Road, Chengdu, 610065, P.R. China

3. Canadian Light Source, Saskatoon, Saskatchewan, Canada

4. Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, Illinois 60439, USA

Abstract

Single rhodium atoms are stabilized on a defective titania support via metal–ligand coordination, which facilitates oxygen activation in the CO oxidation reaction, enables high catalytic performance, and provides long-term stability.

Funder

Argonne National Laboratory

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CY/D4CY00507D

Reference42 articles.

1. Low-Temperature Oxidation of CO over Gold Supported on TiO2, α-Fe2O3, and Co3O4

2. Anionic Single-Atom Catalysts for CO Oxidation: Support-Independent Activity at Low Temperatures

3. Identification of activity trends for CO oxidation on supported transition-metal single-atom catalysts

4. Superior Catalytic Performance of Atomically Dispersed Palladium on Graphene in CO Oxidation

5. Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters