Support effect on Ni-based mono- and bimetallic catalysts in CO2 hydrogenation

Author:

Wang Jihao1,Chen Shilong1ORCID,Ticali Pierfrancesco1ORCID,Summa Paulina2,Mai Simon1,Skorupska Katarzyna2ORCID,Behrens Malte1ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Kiel University, Max-Eyth-Str. 2, 24118 Kiel, Germany

2. Department of Inorganic Chemistry, Fritz-Haber-Institute of the Max-Planck-Society, Faradayweg 4-6, 14195 Berlin, Germany

Abstract

Zirconia- and ceria-supported Ni,Fe catalysts show higher activity than MgO-supported catalysts in CO2 hydrogenation. This effect is due to differences in reducibility and oxygen vacancy formation resulting in modified metal-support interactions.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

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